μ-Oxalato-bis[bis(triphenylphosphine)copper(I)] dichloromethane disolvate1
نویسندگان
چکیده
The dinuclear molecule of the title compound, [Cu(2)(C(2)O(4))(C(18)H(15)P)(4)]·2CH(2)Cl(2), lies across an inversion center with a strictly planar bridging oxalate ligand coordinating two Cu(I) ions via two pairs of O atoms. Two triphenyl-phosphine ligands also coordinate each symmetry-related Cu(I) ion, resulting in a distorted tetra-hedral geometry [O-Cu-O = 80.57 (5)° and P-Cu-P = 125.72 (2)°]. In the crystal, there are two dichloro-methane solvent mol-ecules for each dinuclear complex.
منابع مشابه
μ-Oxalato-bis[bis(triphenylphosphine)copper(I)] dichloromethane disolvate. Corrigendum
An erroneous claim in the paper by Royappa et al. [Acta Cryst. (2013), E69, m126] is corrected and a reference added for a previously published report of a closely related structure.[This corrects the article DOI: 10.1107/S1600536813002080.].
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عنوان ژورنال:
دوره 69 شماره
صفحات -
تاریخ انتشار 2013